New approach to dichloroindium amides

摘要

Two different routes are presented for the synthesis of dichloroindium amides. On the one hand we prepared [THF]_3Li(#mu#-Cl)Cl_2InN(SiMe_3)(Dipp) (1) (Dipp = 2, 6-diisopropylphenyl) by the reaction of indium trichloride with the lithiated aniline, on the other hand Cl_2InNEt_2 (2) by trimethylsilyl chloride elimination. Compound 1 was characterized by X-ray structural analysis.