Metal-centred versus ligand-centred luminescence quenching of a macrocyclic copper(II) complex

摘要

The new macrocyclic ligand trans-6-(9-anthracenylmethylamino)-6, 13-dimethyl-1, 4, 8, 11-tetraazacyclotetradecan-13-amine has been synthesized and characterised as its copper(II) complex and the crystal structure of this complex has been determined. Fluorescence of the anthracenyl group of the macrocycle is quenched in its free base form and when complexed with Cu~(II). Fluorescence returns when Lewis acids such as H~+ and Zn~(2+) are added to solutions of the ligand, indicating that photoinduced electron transfer from the amine lone pairs is responsible for fluorescence quenching in the free base form. By contrast, fluorescence of the complex is quenched by intramolecular electronic energy transfer.