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Degradation of Pesticides Wastewater by Silyl Based Cationic Surfactants

机译:甲硅烷基阳离子表面活性剂降解农药废水

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New stable silayl cationic surfactants have been studied for the destruction of toxic organophosphorus pesticides.Hexadecyl,dodecyl trimethyl silane ammonium chloride or iodide surfactants were synthesized and eval uated in the degradation of pesticides such as Diazinon,Malathion or Chlorpyrifos.The hydrolytic efficiency of each surfactant was tested by measuring the kinetics of model substrates cleavage under a pseudo-first order reaction.The iodo silayl based surfactants showed more destructive power than the chloro derivatives.Meanwhile,the hexadecyl moiety showed more effective pesticide degradation than the corresponding dodecyl moiety.
机译:研究了用于破坏有毒有机磷农药的新型稳定的甲硅烷基阳离子表面活性剂,合成了十六烷基,十二烷基三甲基硅烷氯化铵或碘化物表面活性剂,并对二嗪农,马拉硫磷或毒死rif等农药的降解进行了评估。每种表面活性剂的水解效率通过测量拟一级反应中模型基质裂解的动力学来测试。基于碘甲硅烷基的表面活性剂显示出比氯代衍生物更大的破坏力。同时,十六烷基部分显示出比相应的十二烷基部分更有效的农药降解作用。

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