Association and Solvation of Silver Nitrate and Perchlorate in Aqueous Ethanol

摘要

The molar conductivities of silver nitrate and perchlorate solutions in aqueous ethanol (X (EtOH) = 0.5-0.9 and X (EtOH) = 0.9, respectively) were measured. Using the conductometry data, the values of dissociation constants and limiting conductivities (lambda (0)) of these electrolytes were calculated. The results were discussed by employing a solvation-thermodynamic approach. The hydrodynamic radii of Ag+, and ions were estimated.