Multifunctional superhydrophobic/oleophobic and flame-retardant cellulose fibres with improved ice-releasing properties and passive antibacterial activity prepared via the sol-gel method

摘要

In this research, a two-component sol-gel inorganic-organic hybrid coating was prepared on a cotton fibre surface. An equimolar sol mixture of the precursors 1H,1H,2H,2H-perfluorooctyltriethoxysilane (SiF) and P,P-diphenyl-N-(3-(trimethoxysilyl)propyl) phosphinic amide (SiP) was applied to cotton fabric samples using the pad-dry-cure method. The surfaces of the untreated and coated cotton fibres were characterised using scanning electron microscopy, Fourier transform-infrared spectroscopy, X-ray photoelectron spectroscopy, and time-of-flight-sec-ondary ion mass spectrometry. The functional properties of the coated cotton fabric samples were investigated; using static contact angle measurements with water and n-hexa-decane, the ice-releasing test, antibacterial testing against Gram-positive Staphylococcus aureus and Gram-negative Escherichia coli, thermogravimetric analysis in an air atmosphere, and vertical flammability tests. The results reveal the formation of a nanocomposite two-component inorganic-organic hybrid polymer network that is homog-enously distributed over the cotton fibre surface. The presence of the SiP component in the two-component inorganic-organic hybrid coating did not hinder the functional properties imparted by the presence of the SiF component and vice versa, illustrating their compatibility. The cooperative action of the SiF and SiP components in the two-component coating provided the cotton fabric with exceptional multifunctionality, including simultaneous su-perhydrophobicity and high oleophobicity, passive antibacterial activity, and improved fhermo-oxidative stability.