Adsorption equilibrium and kinetic studies of strontium on Mg-bentonite, Fe-bentonite and illite/smectite

摘要

Radionuclide adsorption on clay rocks has in recent years been studied mainly in connection with their use as sealing barriers in nuclear waste and spent nuclear fuel repositories. In Slovakia we find deposits of bentonites which should be used for the above mentioned purpose. The usability of adsorbents in practical applications depends on the speed of the adsorption process of the adsorbate on the adsorbent surface and distribution ratio. The work objective was the study of the kinetics of Sr adsorption on clay adsorbents with different geological origin. The geological origin of bentonite significantly influences its mineralogical and chemical composition and therein its adsorption properties. The adsorption process of strontium was fast. Adsorption equilibrium was reached for all three samples studied within 1 min from the beginning of the contact between solid and liquid phases. After the adsorption equilibrium was reached there were no more changes in the values of distribution coefficients and the adsorption percentage, and comparable values were reached in the contact-phase time span studied within 10 days. The values of adsorbed strontium were decreasing in the following order: J250 > L250 > DV45. The pseudo second-order kinetic models was used to describe model the kinetic data and provided excellent kinetic data fitting (R ~2 > 0.999).