γ Radiolysis of C_(60) fullerene in water and water/ammonia mixtures: Relevance of fullerene fate in ices of interstellar medium

摘要

The γ radiolysis of fullerene C_(60) dispersed in H _2O, H_2O/NH_3, H_2O/methanol and H _2O/NH_3/methanol was studied at 250 and 500 kGy. It was found that C_(60) originally insoluble in the above mentioned hosting matrix became soluble as a consequence of multiple hydroxylation and oxidation reaction produced by the free radicals generated by the radiolysis of the hosting matrix. The changes undergone by C_(60) were studied by infrared spectroscopy (FT-IR) and by electronic absorption spectroscopy. The astrochemical consequences of the present study are that C_(60) ejected in the interstellar medium for instance from protoplanetary and planetary nebulae can condense together with water and other ices in dense molecular clouds. Under the action of high energy radiation C_(60) reacts with the free radicals generated from the matrix where it is embedded it is solubilized and consequently its carbon content becomes available for further abiotic processes of synthesis of molecules of astrobiological interest. The behavior of C_(60) appears comparable to that of common PAHs which are also hydroxylated and oxidized under similar conditions.