Crystallization Kinetics and Crystallization behavior of Syndiotactic Polystyrene/Clay Nanocomposites

摘要

We investigated the effects of montmorillonite (clay) on the crystallization kinetics of syndiotactic polystyrene (sPS) with isothermal differential scanning calorimetry analyses. The clay was dispersed into the sPH matrix via melt blending on a scale of 1-2 nm or up to about 100 nm, depending on the surfactant treatment. For a crystallization temperature of 240 deg C, the isothermal crystallization data were fitted well with the Avrami crystallization dequation. Crystallization data on the kinetic parameters (i.e., the crystallization rate constant, Avrami exponent, clay content, and clay/surfactant cation-exchange ratio) were also investigated. Experimental results indicated that the crystallization rate constant of the sPS nanocomposite increased with increasing clay content. The clay played a vital role in facilitating the formation on the thermodynamically more favorable all-#beta#-form crystal when the sPS was meltcrystallized.