Amphiphilic Polymer Gel Electrolytes. I. Preparation of Gels Based on Poly(ethylene oxide) Graft Copolymers Containing Different Ionophobic Groups

摘要

Amphiphilic graft copolymers were prepared via the radical copolymerization of poly(ethylene oxide) (PEO) macromonomers with fluorocarbon or hydrocarbon acrylates in toluene with 2, 2'-azobisisobutyronitrile (AIBN) as an initiator. ~1H NMR spectroscopy confirmed that the composition graft copolymers corresponded well to the monomer feed. For gel electrolytes prepared from the amphiphilic copolymers, the mature of the ionophobic parts of the amphiphilic graft copolymers had a great influence on the ion conductivity. Gel electrolytes based on graft copolymers containing fluorocarbon side chains showed significantly higher ion conductivity than electrolytes based on graft copolymers containing hydrocarbon groups. The ambient-temperature ion conductivity was about 2.6 mS/cm at 20 deg C for a gel electrolyte based on an amphiphilic graft copolymer consisting of an acrlyate backbone carrying PEO and fluorocarbon side chains. Corresponding gels based on graft copolymers with PEO side chains and hydrocarbon groups showed an ambient-temperature ion conductivity of about 1.2 mS/cm. The gel electrolytes contained 30 wt % copolymer and 70 wt % 1 M LiPF_6 in an ethylene carbonate/#gamma#-butyrolactone (2/1 w/w) mixture.