The photophysics of salicylic acid derivatives in aqueous solution

摘要

The photophysics of a number salicylic acid derivatives (SADs) in aqueous solutions was investigated in a wide range of pH by time-correlated single photon counting (lambda(ex) = 350 nM, tau(resp) = 300 ps) and fluorescence up-conversion (lambda(ex) = 266 nm, tau(resp) = 300 fs) techniques. The acid-base equilibrium constants in the ground (pK(a)) and the excited states (pK(a)*), the fluorescence quantum yields as well as the lifetimes of anionic, neutral, and cationic forms of SADs were determined. Evidence of ultrafast excited-state intramolecular proton transfer (ESIPT) leading to the formation of the proton-transferred excited state of SADs was obtained from the fluorescence up-conversion measurement. The nature of the ESIPT process is discussed.