Comparative study of p-amino benzhydrazide and m-amino benzhydrazide by free radicals and free electron transfer

摘要

The bimolecular electron transfer fromp-amino benzhydrazide (PABH) and itsmeta-derivative (m-amino benzhydrazide (MABH)) to specific one-electron oxidant results in the formation of anilino radical. In case of PABH, reaction with ?OH radicals results in the synchronous formation of adduct as well as anilino radical. The interesting observation is that the yield of the anilino radical increases with increase in pH. The effect of substitution also has a significant effect on the formation of adduct. In case of MABH, significant yield of anilino radical gets form on reaction with ?OH radical. The free radical electron transfer from PABH and MABH to parent radical cation of non-polar solvent also results in the formation of anilino radical only suggesting that the radical cation of PABH andMABH has short life time. The above results were supported by quantum chemical calculations.