Efficient white organic light-emitting devices based on blue, orange, red phosphorescent dyes

摘要

We demonstrate efficient white organic light-emitting devices (WOLEDs) based on an orange phosphorescent iridium complex bis(2-(2-fluorphenyl)-1,3-benzothiozolato-N, C-2') iridium( acetylacetonate) in combination with blue phosphorescent dye bis[(4, 6-difluorophenyl)-pyridinato-N, C-2)](picolinato) Ir(III) and red phosphorescent dye bis[1-(phenyl)isoquinoline] iridium (III) acetylanetonate. By introducing a thin layer of 4, 7-diphenyl-1,10-phenanthroline between blue and red emission layers, the diffusion of excitons is confined and white light can be obtained. WOLEDs with the interlayer all have a higher colour rendering index (> 82) than the device without it (76). One device has the maximum current efficiency of 17.6 cdA(-1) and a maximum luminance of 39 050 cd m(-2). The power efficiency is 8.7 lmW(-1) at 100 cd m(-2). Furthermore, the device has good colour stability and the CIE coordinates just change from (0.394, 0.425) to (0.390, 0.426) with the luminance increasing from 630 to 4200 cd m(-2).