Corrosion behavior of Inconel 690 and 693 in an iron phosphate melt

摘要

The corrosion resistance of Inconel 690 and 693 coupons submerged in an iron phosphate melt has been investigated. After 155 days in an iron phosphate melt at 1050degreesC. which contained 30wt% of a simulated low activity waste (LAW at Hanford), the weight loss of Inconel 690 and 693 was 14% and 8%, respectively. The overall corrosion rate, calculated from the initial and final dimensions of each coupon, was 1.3 and 0.7mum/day for the Inconel 690 and 693, respectively. Scanning electron microscopy and X-ray diffraction of the submerged Inconel coupons after 155 days in the iron phosphate melt showed that an altered surface layer had formed which was depleted in nickel and consisted of a (Fe, Cr)(2)O-3 solid solution. This altered layer appears to be chemically protective as indicated by the gradual reduction in weight loss which occurred with time in the iron phosphate melt. Inconel 693 appears to be a better candidate to use as an electrode in iron phosphate melts since its corrosion rate and weight loss was only about one half that of Inconel 690. (C) 2004 Elsevier B.V. All rights reserved.