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A study of early corrosion behaviors of FeCrAl alloys in liquid lead-bismuth eutectic environments

机译:FeCrAl合金在液态铅铋共晶环境中的早期腐蚀行为研究

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摘要

Lead and lead-bismuth eutectic (LBE) alloy have been increasingly receiving attention as heavy liquid metal coolants (HLMC) for future nuclear energy systems. The compatibility of structural materials and components with lead-bismuth eutectic liquid at high temperature is one of key issues for the commercialization of lead fast reactors. In the present study, the corrosion behaviors of iron-based alumina-forming alloys (Kanthal-AF?, PM2000, MA956) were investigated by exposing to stagnant LBE environments at 500 °C and 550 °C for up to 500 h. After exposures, the thickness and chemistry of the oxide layer on the specimens were analyzed by scanning electron microscopy, scanning transmission electron microscopy and energy dispersive X-ray spectroscopy. As a result, the oxide characteristics and the corrosion resistance were compared. In this study, it was shown that the corrosion resistance of FeCrAl ODS steels (PM2000, MA956) are superior to that of FeCrAl ferritic steel (Kanthal-AF?) in higher temperature LBE.
机译:铅和铅铋共晶(LBE)合金作为用于未来核能系统的重液态金属冷却剂(HLMC)越来越受到关注。结构材料和组件与铅-铋共晶液体在高温下的相容性是铅快速反应器商业化的关键问题之一。在本研究中,通过将铁基氧化铝形成合金(Kanthal-AF?,PM2000,MA956)暴露在停滞的LBE环境中(在500°C和550°C下长达500小时)的腐蚀行为进行了研究。曝光后,通过扫描电子显微镜,扫描透射电子显微镜和能量色散X射线光谱法分析样品上的氧化层的厚度和化学性质。结果,比较了氧化物特性和耐腐蚀性。在这项研究中,表明在较高的LBE温度下,FeCrAl ODS钢(PM2000,MA956)的耐蚀性优于FeCrAl铁素体钢(Kanthal-AF?)。

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