Inferring organic content of sediments by scanning reflectance spectroscopy (380-730 nm): Applying a novel methodology in a case study from proglacial lakes in Norway

摘要

Reflectance spectroscopy in the visible spectrum (VIS-RS) is a method that has been successfully applied for inferring organic content of sediments. In this study, we test the applicability of VIS-RS to lake sediments in Norway. On the one hand we use conventional, established algorithms for inferring organic content of sediments, on the other hand we test the potential of multivariate calibration techniques to infer organic content. For absolute quantification of organic content, conventional C_(org) measurements are needed when using conventional algorithms as well as when employing multivariate calibration techniques. Both, conventional algorithms and multivariate calibrations, result in estimates of organic content closely mirroring loss-on-ignition measurements. When using multivariate calibration techniques, a conventional C_(org) measurement every 5 cm is sufficient to obtain estimates of organic matter that are more accurate than those obtained by means of conventional algorithms. Therefore, the potential of multivariate calibration techniques and VIS-RS to substitute measurements of more time consuming and costly sediment parameters (e.g. clay minerals) should be tested.