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首页> 外文期刊>Journal of Molecular Structure >An infrared and Raman spectroscopic study of the Hofmann-T_d-type 1,4-dioxane clathrates: M(NH_3)_2M'(CN)_4.2C_4H_8O_2 (M = Mn or Cd, M' = Hg; M = Cd, M' = Cd)
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An infrared and Raman spectroscopic study of the Hofmann-T_d-type 1,4-dioxane clathrates: M(NH_3)_2M'(CN)_4.2C_4H_8O_2 (M = Mn or Cd, M' = Hg; M = Cd, M' = Cd)

机译:霍夫曼-T_d型1,4-二恶烷包合物的红外和拉曼光谱研究:M(NH_3)_2M'(CN)_4.2C_4H_8O_2(M = Mn或Cd,M'= Hg; M = Cd,M' = Cd)

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摘要

Three new Hofmann-T_d-type clathrates of the form M(NH_3)_2M'(CN)_4.2C_4H_8O_2 (M = Mn or Cd, M' = Hg; M = Cd, M' = Cd) were prepared, and their IR and Raman spectra are reported. The spectral data suggest that the host frame-works of these compounds are similar to those of Hofmann-T_d-type benzene clathrates.
机译:准备了三个新的形式为M(NH_3)_2M'(CN)_4.2C_4H_8O_2(M = Mn或Cd,M'= Hg; M = Cd,M'= Cd)的霍夫曼-T_d型包合物,并对其IR进行了表征和拉曼光谱被报道。光谱数据表明,这些化合物的主体构架与霍夫曼-T_d型苯包合物的构架相似。

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