Gating Characteristics of Thermo-Responsive Membranes with Grafted Linear and Crossiinked Poly(N-isopropylacrylamide)Gates

摘要

Thermo-responsive porous membranes with grafted linear and crossiinked poly(IV-isopropylacrylamide)(PNIPAM)gates are successfully prepared at temperatures above and below the lower critical solution temperature(LCST)of PNIPAM by using a plasma-induced grafting polymerization method,and the effects of operation pressure and grafting temperature on the thermo-responsive gating characteristics of the prepared membranes are investigated systematically.The fluxes of water through the grafted membranes increase simply with increasing the operation pressure no matter whether the environmental temperature is 40 °C or 25 °C.Under high operation pressure(e.g.,higher than 0.14 MPa),the grafted linear PNIPAM gates deform to a certain extent,whereas the grafted crossiinked PNIPAM gates do not deform.For both membranes with grafted linear and crossiinked PNIPAM gates,the membranes prepared at 25 °C(below the LCST of PNIPAM)show larger thermo-responsive gating coefficients than those prepared at 40 °C(above the LCST of PNIPAM),which results from different distributions of grafted PNIPAM gates in the membrane pores.When the PNIPAM gates are grafted at 25 °C,the grafted layer near the membrane surface is much thicker than that inside the membrane pores;on the other hand,when the PNIPAM gates are grafted at 40 °C,the grafted layer is homogeneously formed throughout the whole pore length.Both linear and crossiinked grafted PNIPAM gates in the membrane pores exhibit stable and repeatable thermo-responsive"open-close"switch performances under the operation pressure of 0.26 MPa.The results in this study provide valuable guidance for designing,fabricating,and operating thermo-responsive gating membranes with desirable performances.