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The impurities effect on thermal degradation and corrosivity of amine solution in South Pars gas sweetening plants

机译:杂质对South Pars气体脱硫装置中胺溶液的热降解和腐蚀性的影响

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摘要

Large amount of thermal degraded products, heat stable salts, oxygen and CO2 presence in amine so-) lution, is the main causes of corrosion problems in the gas processing plant. Recent inspection of the gas; sweetening process equipment showed that significant corrosion has occurred in the bottom sections of i the rich amine regenerators and reboilers as well as the piping connecting the reboilers and the re-; generators. Corrosion resulted in a leak in the vapor return line from the reboiler to regenerator. The; object of the present investigation is (a) to focus on the Different impurity in amine cycle and insights' that have been gained from observations of sour gas sweetening processes in South Pars gas processing; plant (b) to discuss the effect of impurities on the thermal degradation and corrosivity of amine solution (c) to analyze some of the volatile degradation products by mass spectrometry and (d) from the available experimental evidence suggest a corrosion prevention method.
机译:大量的热降解产物,热稳定的盐,在胺溶液中存在的氧气和CO2是气体处理厂腐蚀问题的主要原因。最近检查气体;脱硫工艺设备显示,富胺再生器和再沸器的底部以及连接再沸器和再沸器的管道已经发生了明显的腐蚀。发电机。腐蚀导致从再沸器到再生器的蒸汽回流管线泄漏。的;本研究的目的是(a)着重研究胺循环中的不同杂质以及从南帕尔斯天然气加工中的酸性气体脱硫过程的观察中获得的见解; (b)讨论杂质对胺溶液的热降解和腐蚀性的影响(c)通过质谱分析某些挥发性降解产物,(d)从现有的实验证据中提出一种防腐蚀方法。

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