首页> 外文期刊>Journal of new materials for electrochemical systems >Voltammetric Studies of Anthracen-9-ylmethylene-(3,4-dimethyl-isoxazol-5-y1)-amine Compound at Platinium Electrode
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Voltammetric Studies of Anthracen-9-ylmethylene-(3,4-dimethyl-isoxazol-5-y1)-amine Compound at Platinium Electrode

机译:铂电极上蒽-9-基亚甲基-(3,4-二甲基-异恶唑-5-y1)-胺化合物的伏安研究

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摘要

The voltammetric behavior of anthracen-9-ylmethylene-(3,4-dimethyl-isoxazol-5-yl)-amine compound at Platiniuni electrode has been performed via convolutive cyclic voltammetry and digital simulation techniques using a conventional platinium electrode in 0.1 mol L-1 tetrabutylammonium perchlorate (TBAP) in acetonitrile solvent (CH3CN). The compound loss one electron forming radical cation followed by fast chemical step and the radical cation loss another two electrons producing trication which followed by chemical reaction (ECEC). Cyclic voltammetry and convolutive voltammetry were used for determination of the chemical and the electrochemical parameters of the electrode reaction pathway of the investigated compound. The Electrochemical parameters such as alpha, ks, E degrees, D, and kc of the investigated isoxazol derivative were verified via digital simulation technique. Voltammetric studies of the investigated isoxazol derivative compound under consideration was presented and discussed.
机译:蒽9-基亚甲基-(3,4-二甲基-异恶唑-5-基)-胺类化合物在Platiniuni电极上的伏安行为已通过卷积循环伏安法和数字模拟技术进行了测定,使用传统的铂电极在0.1 mol L- 1在乙腈溶剂(CH3CN)中的高氯酸四丁铵(TBAP)。该化合物损失一个电子形成的自由基阳离子,然后进行快速化学步骤,该自由基阳离子损失另外两个电子产生的三阳离子,随后进行化学反应(ECEC)。使用循环伏安法和卷积伏安法测定所研究化合物的电极反应途径的化学和电化学参数。通过数字仿真技术验证了所研究的异恶唑衍生物的电化学参数,如α,ks,E度,D和kc。提出并讨论了所研究的异恶唑衍生物化合物的伏安研究。

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