Synthesis and self-assembly of 5,5 '-bis(phenylethynyl)-2,2 '-bithiophene-based bolapolyphiles in triangular and square LC honeycombs

摘要

A series of X-shaped 5,5'-bis(phenylethynyl)-2,2'-bithiophene-based bolaamphiphiles bearing two long lateral alkyl chains and two terminal glycerol groups has been synthesized by using Kumada and Sonogashira coupling reactions as key steps. The thermotropic liquid crystalline behavior of these compounds was investigated by POM, DSC and X-ray scattering. With elongation of the lateral alkyl chains two different kinds of liquid crystalline phases with honeycomb structures, Col(hex)Delta/p6mm, formed by (defective) triangular honeycomb cells, and Col(squ)/p4mm with square cells were observed for these compounds. UV and PL measurements indicate fluorescent properties making them potential candidates for application in fluorescence sensor devices.