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Emerging strategies for the synthesis of monodisperse colloidal semiconductor quantum rods

机译:单分散胶体半导体量子棒合成的新兴策略

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Colloidal semiconductor quantum rods are exciting materials from both fundamental and technological points of view. The electronic and optical properties of these materials are governed by the decrease in the confinement of charge carriers along the long axis and by the cylindrical symmetry of the particles. Their intrinsic properties, such as highly controlled optical characteristics, are advantageous in biological labeling, photovoltaic devices and light emitting diodes. Thanks to the advances in the development of strategies for synthesizing colloidal semiconductor quantum rods that made these materials available. The availability of colloidal semiconductor quantum rods provides a platform for both the investigation of their stimulating properties and the exploration of their promising applications. This review article focuses on the recent advances in the strategies for the synthesis of monodisperse colloidal semiconductor quantum rods. The fundamental issues associated with the anisotropic growth of colloidal nanocrystals such as facet, surface energy, selective binding of the surfactant, growth kinetics and thermodynamics were addressed, interpreted and discussed. Synthetic strategies for colloidal semiconductor quantum rods, being different from one another, were introduced and the growth mechanisms were revealed. The progress on the synthetic strategies of colloidal semiconductor quantum rods provided the basis for many inspiring applications in the fields of photocatalysis, opto-electronic devices, bio-labeling and other advanced applications.
机译:从基础和技术的角度来看,胶体半导体量子棒都是令人兴奋的材料。这些材料的电子和光学特性受沿长轴方向的载流子限制的减小以及颗粒的圆柱对称性的影响。它们的固有特性,例如高度受控的光学特性,在生物标记,光伏设备和发光二极管中是有利的。得益于合成胶体半导体量子棒策略的发展,这些材料使这些材料变得可用。胶体半导体量子棒的可用性为研究其激发特性和探索其有希望的应用提供了一个平台。本文将重点介绍单分散胶体半导体量子棒合成策略的最新进展。涉及,解释和讨论了与胶体纳米晶体的各向异性生长有关的基本问题,例如刻面,表面能,表面活性剂的选择性结合,生长动力学和热力学。介绍了胶体半导体量子棒彼此不同的合成策略,并揭示了其生长机理。胶体半导体量子棒合成策略的进展为光催化,光电器件,生物标记和其他高级应用领域中的许多启发性应用提供了基础。

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