One-pot synthesis of ultrasmall MoO3 nanoparticles supported on SiO2, TiO2, and ZrO2 nanospheres: an efficient epoxidation catalyst

摘要

Ultrasmall molybdenum oxide (MoO3) nanoparticles supported on various (SiO2, TiO2 or ZrO2) nanospheres were synthesized in one pot using a reverse micelle method. The prepared catalysts were thoroughly characterized by various physico-chemical methods. TEM images showed uniform dispersion of MoO3 nanoparticles (1.5-4 nm) onto silica (~275 nm). No separate MoO3 particles were identified from TEM for MoO3/TiO2 (~10.5 nm) and MoO3/ZrO2 (~6.5 nm) because AHM reacted with titanium and zirconium hydroxides to form solid solution. Among the prepared catalysts MoO3/SiO2 showed excellent catalytic activity (up to 90% conversion and 100% epoxide selectivity) for olefin epoxidation. The catalyst was successfully recycled up to five cycles without losing much activity and selectivity.