Thermal Properties of Fe-octacarboxyl Acid Phthalocyanine/Polyurethane Blends

摘要

The thermal stability of PU has been a critical factor to influence its applications as engineering materials. In this paper, the thermal properties of Fe-octacarboxyl acid phthalocyanine (Fe-OCAP)/polyurethane (PU) blends were investigated. The glass transition temperatures (T-g) of Fe-OCAP/PU blends were analyzed by differential scanning calorimetry (DSC). The results showed that with increasing Fe-OCAP content up to 10% T-g of the samples decreased. Thermal stability of the samples was studied by thermogravimetric analysis (TGA). The decrease of the degradation rate of the samples with increasing Fe-OCAP content indicated an improvement of thermal stability for the modified samples. The activation energy of thermal degradation was calculated by the Freeman and Carroll method. The results showed that the activation energy increased with increasing Fe-OCAP content, which also indicated the improved thermal stability obtained in the modified samples. The thermal properties of the samples were influenced by the incorporation of Fe-OCAP.