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首页> 外文期刊>Chinese journal of chemical physics >Correspondence Between Quantum and Classical Dynamics in Photodetachment Near Elastic Wall
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Correspondence Between Quantum and Classical Dynamics in Photodetachment Near Elastic Wall

机译:弹性壁附近光解离的量子力学与经典动力学的对应关系

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摘要

The photodetachment of H~-near an elastic wall was investigated and an analytical formula of the cross section was derived. It was found that the cross section is a superposition of a smooth background and sinusoidal oscillation,which depends on the distance between the ion and the elastic wall. The classical dynamics of the photo-detached electron and its quantum correspondence was analyzed. In this model,the semiclassical photodetachment cross section is exactly the same as the quantum result.
机译:研究了H〜在弹性壁附近的光解,得出了截面的解析公式。发现该横截面是光滑背景和正弦振动的叠加,这取决于离子与弹性壁之间的距离。分析了光解电子的经典动力学及其量子对应关系。在该模型中,半经典光解横截面与量子结果完全相同。

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