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Synthesis and characterization of mesoporous anatase TiO2 nanostructures via organic acid precursor process for dye-sensitized solar cells applications

机译:通过有机酸前体工艺合成和表征介孔锐钛矿型TiO2纳米结构,用于染料敏化太阳能电池

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摘要

Titania (TiO2) nanoparticles have been synthesized using organic precursor technique. The titania nanoparticles were characterized. The results indicated that the prepared titanium oxalate and citrate precursors were transformed to anatase TiO2 phase at temperature 400 °C for 2 h. Dye-sensitized solar cells were assembled using the prepared nanocrystalline TiO2 with large surface area. The specific surface area S_(BET)was 80.9 and 78.6 m~2/g using oxalic and citric acids, respectively. The power efficiency was 3.5 and 2.4%. A brief discussion on the possible reasons behind the low power conversion efficiency observed for these type of solar cells was reported.
机译:二氧化钛(TiO2)纳米粒子已使用有机前体技术合成。表征了二氧化钛纳米颗粒。结果表明,所制得的草酸钛和柠檬酸钛前驱体在400°C的温度下转化为锐钛矿型TiO2相2 h。使用制备的具有大表面积的纳米晶体TiO2组装染料敏化太阳能电池。使用草酸和柠檬酸的比表面积S_(BET)分别为80.9和78.6 m〜2 / g。功率效率分别为3.5和2.4%。报告了有关在这类太阳能电池中观察到的低功率转换效率背后的可能原因的简短讨论。

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