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A TEM study of non-parallel twins inducing thickness growth in silver chloride {111} tabular crystals

机译:TEM研究非平行孪晶诱导氯化银{111}平板状晶体的厚度增长

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摘要

Defects in AgCl tabular grains with {111} surfaces are characterized by transmission electron microscopy (TEM) and their influence on the growth process is discussed. In the tabular crystals, twins parallel to the tabular face as well as dislocations along different directions are observed. The twins induce the tabular growth, while the dislocations do not influence the morphology. In 10 to 30% of the crystals that have been characterized, thickness growth is observed and it is shown that in all cases twins on other planes than the tabular ones are present. Two configurations occur more frequently and are analyzed in detail. For the first group, twins parallel to the tabular face as well as a microtwin along a non-parallel {111} plane that ends inside the crystal are present. In the crystals of the second group, only one extra non-parallel twin occurs giving rise to a bicrystal built up by a tetrahedral shaped part and a flat triangular or trapezoidal part. More complex twin configurations give rise to various, less characteristic morphologies. From these observations, it appears that the thickness growth is related to the presence of the twins on planes other than on the tabular ones. [References: 19]
机译:用透射电子显微镜(TEM)表征了具有{111}表面的AgCl平板状晶粒中的缺陷,并讨论了它们对生长过程的影响。在板状晶体中,观察到平行于板状面的孪晶以及沿不同方向的位错。双胞胎诱导板状生长,而位错不影响形态。在已表征的10%至30%的晶体中,观察到了厚度的增长,并且表明在所有情况下,在非平板状平面上都存在孪晶。两种配置会更频繁地出现并进行详细分析。对于第一组,存在平行于板状表面的孪晶以及沿晶体内部终止的不平行{111}平面的微孪晶。在第二组晶体中,仅出现一个额外的非平行孪晶,从而产生了由四面体形部分和平坦的三角形或梯形部分构成的双晶。更复杂的孪生结构会产生各种特征较少的形态。从这些观察结果来看,似乎厚度的增长与孪晶在平板状以外的平面上的存在有关。 [参考:19]

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