ENZYMATIC RESOLUTION OF TRANS-2,3-DIHYDRO-3-HYDROXY-2-PHENYL-4H-1-BENZOPYRAN-4-ONE (TRANS-FLAVANON-3-OL) BY LIPASE

Izumi T.; Murakami S.

首页> 外文期刊>Journal of Heterocyclic Chemistry: The International Journal of Heterocyclic Chemistry >ENZYMATIC RESOLUTION OF TRANS-2,3-DIHYDRO-3-HYDROXY-2-PHENYL-4H-1-BENZOPYRAN-4-ONE (TRANS-FLAVANON-3-OL) BY LIPASE

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ENZYMATIC RESOLUTION OF TRANS-2,3-DIHYDRO-3-HYDROXY-2-PHENYL-4H-1-BENZOPYRAN-4-ONE (TRANS-FLAVANON-3-OL) BY LIPASE

机译：脂肪酶的酶法拆分反式-2,3-二氢-3-羟基-2-苯基-4H-1-苯并吡喃-4-酮（反式-黄烷-3-OL）

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trans-2,3-Dihydro-3-hydroxy-2-phenyl-4H-1-benzopyran-4-one (trans-flavanon3-ol) was resolved to acetate of (2S,3S)-(-)-trans-flavanon-3-ol and (2R,3R)-(-)-trans-flavanon-3-ol by an enzymatic transesterification with vinyl acetate in the presence of Pseudomonas cepacia lipase. [References: 23]

机译：将反式-2,3-二氢-3-羟基-2-苯基-4H-1-苯并吡喃-4-酮（反式黄酮3-醇）拆分为（2S，3S）-（-）-反式黄酮的乙酸盐在洋葱假单胞菌脂肪酶存在下，通过与乙酸乙烯酯的酶促酯基转移反应生成-3-ol和（2R，3R）-（-）-反式-黄酮-3-醇。 [参考：23]

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来源
《Journal of Heterocyclic Chemistry: The International Journal of Heterocyclic Chemistry》 |1995年第4期|共3页
作者
Izumi T.; Murakami S.;
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原文格式 PDF
正文语种 eng
中图分类有机化学;
关键词
Organic-synthesis; Heterocycles; Flavanonols; Derivatives; Alcohols; Enzymes;

机译：有机合成;杂环;黄烷醇;衍生物;醇;酶;
入库时间 2022-08-19 01:38:44

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1. ENZYMATIC RESOLUTION OF TRANS-2,3-DIHYDRO-3-HYDROXY-2-PHENYL-4H-1-BENZOPYRAN-4-ONE (TRANS-FLAVANON-3-OL) BY LIPASE [J] . Izumi T., Murakami S. Journal of Heterocyclic Chemistry: The International Journal of Heterocyclic Chemistry . 1995,第4期

机译：脂肪酶的酶法拆分反式-2,3-二氢-3-羟基-2-苯基-4H-1-苯并吡喃-4-酮（反式-黄烷-3-OL）
2. Enzymatic resolution of diltiazem intermediate by Serratia marcescens lipase: molecular mechanism of lipase secretion and its industrial application [J] . Takeji Shibatani, Kenji Omori, Hiroyuki Akatsuka, Journal of molecular catalysis, B. Enzymatic . 2000,第1a3期

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ENZYMATIC RESOLUTION OF TRANS-2,3-DIHYDRO-3-HYDROXY-2-PHENYL-4H-1-BENZOPYRAN-4-ONE (TRANS-FLAVANON-3-OL) BY LIPASE

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