Mn(III) acetate mediated diasteroselective [3+2] oxidative addition of 1,3-dicarbonyl compounds with chalcones

Shanmugam P; Kumar KH; Perumal PT

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Mn(III) acetate mediated diasteroselective [3+2] oxidative addition of 1,3-dicarbonyl compounds with chalcones

机译：乙酸锰（III）介导的1，3-二羰基化合物与查耳酮的非对映选择性[3 + 2]氧化加成

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摘要

A diastereoselective synthesis of 4,5-dihydrofurans by oxidative addition of 1,3-dicarbonyl compounds with chalcones mediated by Mn(OAc)(3) in moderate to good yields is reported.

机译：报道了一种非对映选择性合成4,5-二氢呋喃的方法，该方法是将1,3-二羰基化合物与由Mn（OAc）（3）介导的查耳酮氧化加成，合成产率中等至良好。

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《Journal of Heterocyclic Chemistry: The International Journal of Heterocyclic Chemistry》 |2007年第4期|共4页
作者
Shanmugam P; Kumar KH; Perumal PT;
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正文语种 eng
中图分类有机化学;
关键词
CERIUM(IV) AMMONIUM-NITRATE; MANGANESE(III) ACETATE; RADICAL CYCLIZATION; CYCLOADDITION; DIHYDROFURANS; ALKENES; DERIVATIVES; OLEFINS; KETONES;

机译：硝酸铈（IV）;醋酸锰（III）;自由基循环;循环负载;二呋喃;烯烃;衍生物;烯烃;酮;

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1. Mn(III) acetate mediated diasteroselective [3+2] oxidative addition of 1,3-dicarbonyl compounds with chalcones [J] . Shanmugam P, Kumar KH, Perumal PT Journal of Heterocyclic Chemistry: The International Journal of Heterocyclic Chemistry . 2007,第4期

机译：乙酸锰（III）介导的1，3-二羰基化合物与查耳酮的非对映选择性[3 + 2]氧化加成
2. MANGANESE(III)ACETATE MEDIATED OXIDATIVE FREE RADICAL REACTIONS BETWEEN INDOLE DERIVATIVES AND 1,3-DICARBONYL COMPOUNDS [J] . An-I Tsai, Chia-Hui Lin, Che-Ping Chuang Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2005,第10期

机译：锰（III）乙酸酯介导的吲哚衍生物与1,3-二羰基化合物之间的氧化自由基反应
3. Manganese(III)-mediated oxidative free-radical additions of 1,3-dicarbonyl compounds to homobenzonorbornadiene and benzobarrelene: mechanistic studies [J] . Ali MF, Caliskan RA, Sahin E, Tetrahedron . 2009,第7期

机译：锰（III）介导的1,3-二羰基化合物向均苯并降冰片二烯和苯并桶烯的氧化自由基加成反应：机理研究
4. Umpolung of Chloride Reactivity: (Diacetoxyiodo)benzene Mediated Electrophilic Halogenation of 1,3-dicarbonyl Compounds [C] . Ramulu Akula, Marc J. Galligan, Hasim Ibrahim European Symposium on Organic Chemistry . 2009

机译：氯化物反应性的umpolung :(二乙酰氧基奥）苯介导的1,3-二羰基化合物的亲电卤化
5. Oxidative Transformations of 1,3-Dicarbonyl Compounds by IBX in Various Solvent Systems [D] . Poreddy, Shashidhar. 2016

机译：IBX在各种溶剂系统中的1,3-二羰基化合物的氧化转化
6. Mn(III)-Initiated Facile Oxygenation of Heterocyclic 13-Dicarbonyl Compounds [O] . Md. Taifur Rahman, Md. Aminul Haque, Hikaru Igarashi, 2011

机译：Mn（III）引发的杂环13-二羰基化合物的简易氧化
7. Regio- and diastereoselective synthesis of trans-dihydrofuran-3-carboxamides by radical addition of 1,3-dicarbonyl compounds to acrylamides using manganese(III) acetate and determination of exact configuration by X-ray crystallography [O] . Mehmet Yilmaz, Asli Ustalar, Bedriye Ucan, 2017

机译：使用锰（III）乙酸盐的自由基加入1,3-二羰基化合物对丙烯酰胺的基础氢呋喃-3-羧酰胺的重组和非映选择性合成丙烯酰胺，并通过X射线晶体测定精确构型

Mn(III) acetate mediated diasteroselective [3+2] oxidative addition of 1,3-dicarbonyl compounds with chalcones

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