1,3-Dipolar Cycloaddition of Nitrile Oxides to Methyl 3-(P-Nitrobenzoyloxy)acrylate:Methyl 3-(p-Nitrobenzoyloxy)acrylate as A Methyl Propiolate Equivalent with Reverse Regioselectivity

Kyukwan Zong; Seung II Shin; Dong Ju Jeon; Jung No Lee; Eung K.Ryu

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1,3-Dipolar Cycloaddition of Nitrile Oxides to Methyl 3-(P-Nitrobenzoyloxy)acrylate:Methyl 3-(p-Nitrobenzoyloxy)acrylate as A Methyl Propiolate Equivalent with Reverse Regioselectivity

机译：氧化腈与1,3-偶氮苯环氧基加成到3-（对硝基苯甲酰氧基）丙烯酸甲酯：3-（对硝基苯甲酰氧基）丙烯酸甲酯作为丙炔酸甲酯，具有反向区域选择性

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3-Aryl-4-methoxycarbonylisoxazoles were prepared from the reaction of a variety of substituted benzonitrile oxides with emthyl 3-(p-nitrobenzoyloxy)acrylate in moderate to good yields.

机译：3-芳基-4-甲氧基羰基异恶唑是由各种取代的苯甲腈氧化物与3-（对硝基苯甲酰氧基）丙烯酸乙基酯反应制得的，产率中等至良好。

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《Journal of Heterocyclic Chemistry: The International Journal of Heterocyclic Chemistry》 |2000年第1期|共5页
作者
Kyukwan Zong; Seung II Shin; Dong Ju Jeon; Jung No Lee; Eung K.Ryu;
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1. 1,3-Dipolar Cycloaddition of Nitrile Oxides to Methyl 3-(P-Nitrobenzoyloxy)acrylate:Methyl 3-(p-Nitrobenzoyloxy)acrylate as A Methyl Propiolate Equivalent with Reverse Regioselectivity [J] . Kyukwan Zong, Seung II Shin, Dong Ju Jeon, Journal of Heterocyclic Chemistry: The International Journal of Heterocyclic Chemistry . 2000,第1期

机译：氧化腈与1,3-偶氮苯环氧基加成到3-（对硝基苯甲酰氧基）丙烯酸甲酯：3-（对硝基苯甲酰氧基）丙烯酸甲酯作为丙炔酸甲酯，具有反向区域选择性
2. Theoretical analysis of the regioselectivity of 1,3-dipolar cycloaddition of C-(methoxycarbonyl)-N-methyl with methyl acrylate and vinyl acetate [J] . Benchouk W, Mekelleche SM Journal of Molecular Structure. Theochem: Applications of Theoretical Chemistry to Organic, Inorganic and Biological Problems . 2008,第1a3期

机译：C-（甲氧基羰基）-N-甲基与丙烯酸甲酯和乙酸乙烯酯的1,3-偶极环加成反应区域选择性的理论分析
3. DFT-HSAB prediction of regioselectivity in 1,3-dipolar cycloadditions: Behavior of (4-substituted)benzonitrile oxides towards methyl propiolate [J] . Ponti A, Molteni G Chemistry: A European journal . 2006,第4期

机译：DFT-HSAB预测1,3-偶极环加成中的区域选择性：（4-取代的）苄腈氧化物对丙酸甲酯的行为
4. Stereoselectivity and Regioselectivity of the Cycloaddition Dimerization of allyl 3-(2-pyridyl) acrylate and allyl 3-(2-pyrryl) acrylate: DFT Calculations [C] . Haydar A. Mohammad Salim, Hassan H. Abdallah, P. Ramasami International Conference on Materials Engineering and Science . 2019

机译：烯丙基3-（2-吡啶基）丙烯酸烯烃和烯丙基3-（2-吡啶烯酮）丙烯酸酯：DFT计算的立体选择性和区域选择性：DFT计算
5. Keggin-Type Catalysts Partially Oxidize 2-Methyl-1,3- Propanediol to Methacrylic Acid in a Micro-Fluidized Bed Reactor [D] . Darabi Mahboub, Mohammad Jaber. 2018

机译：Keggin型催化剂在微流化床反应器中部分将2-甲基-1,3-丙二醇部分氧化成甲基丙烯酸
6. Crystal structures of methyl (E)-3-(2-chlorophenyl)-2-({2-(E)-2-nitrovinylphenoxy}methyl)acrylate and methyl (E)-2-({4-chloro-2-(E)-2-nitrovinylphenoxy}methyl)-3-(2-chlorophenyl)acrylate [O] . G. Vimala, N. Poomathi, P. T. Perumal, 2016

机译：（E）-3-（2-氯苯基）-2-（{2-（（E）-2-硝基乙烯基）苯氧基}甲基）丙烯酸甲酯和（E）-2-（{4-氯-甲基2-（（E）-2-硝基乙烯基苯氧基}甲基）-3-（2-氯苯基）丙烯酸酯
7. Crystal structures of methyl (E)-3-(2-chlorophenyl)-2-({2-[(E)-2-nitrovinyl]phenoxy}methyl)acrylate and methyl (E)-2-({4-chloro-2-[(E)-2-nitrovinyl]phenoxy}methyl)-3-(2-chlorophenyl)acrylate [O] . G. Vimala, N. Poomathi, P. T. Perumal, 2016

机译：（E）-3-（2-氯苯基）-2 - （{2 - [（E）-2-硝基乙烯基]苯氧基}甲基）丙烯酸甲酯和（E）-2 - （{4-氯 - 甲基）的晶体结构2 - [（E）-2-硝基乙烯基]苯氧基}甲基）-3-（2-氯苯基）丙烯酸酯
8. Synthesis and Characterization of Poly(Oxy(2-Methyl-1,3-Phenylene)-Oxyisophthaloyl-b-(2-Methyl-1,3- Phenylene)Oxyterephthaloyl)Oxy. [R] . Polk, M. B., Onwumere, F. C. 1984

机译：聚（氧（2-甲基-1,3-亚苯基） - 氧代间苯二酰基-b-（2-甲基-1,3-亚苯基）氧对苯二甲酰基）氧基的合成和表征。

1,3-Dipolar Cycloaddition of Nitrile Oxides to Methyl 3-(P-Nitrobenzoyloxy)acrylate:Methyl 3-(p-Nitrobenzoyloxy)acrylate as A Methyl Propiolate Equivalent with Reverse Regioselectivity

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