Heterocyclic and acyclic azadiene Diels-Alder reactions: Total synthesis of nothapodytine B

Boger DL.

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Heterocyclic and acyclic azadiene Diels-Alder reactions: Total synthesis of nothapodytine B

机译：杂环和无环氮杂二烯Diels-Alder反应：非轻石B的全合成

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摘要

A summary of the applications of the inverse electron demand Diels-Alder reactions of heterocyclic and acyclic azadienes in the total synthesis of natural products is provided and a recent application in the total synthesis of nothapodytine B (mappicine ketone) is presented in detail. [References: 70]

机译：概述了杂环和无环氮杂二氮烯的逆电子需量Diels-Alder反应在天然产物的总合成中的应用，并详细介绍了在非七丁香B（马皮甲酮）的总合成中的最新应用。 [参考：70]

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《Journal of Heterocyclic Chemistry: The International Journal of Heterocyclic Chemistry》 |1998年第5期|共9页
作者
Boger DL.;
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正文语种 eng
中图分类有机化学;
关键词
Formal total synthesis; Thermal cycloaddition; Dimethyl "1; 2; 4; 5-tetrazine-3; 6-dicarboxylate; 4-pi participation; (-)-pyrimidoblamic acid; Room-temperature; Duocarmycin sa; Methyl-ester; Ring-system; Pde-ii;

机译：正式合成;热环加成;“ 1;2;4;5-四嗪-3;6-二羧酸二甲酯;4-pi参与;（-）-嘧啶溴酸;室温;杜卡霉素sa;甲基酯;环-系统;Pde-ii;

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1. Heterocyclic and acyclic azadiene Diels-Alder reactions: Total synthesis of nothapodytine B [J] . Boger DL. Journal of Heterocyclic Chemistry: The International Journal of Heterocyclic Chemistry . 1998,第5期

机译：杂环和无环氮杂二烯Diels-Alder反应：非轻石B的全合成
2. Catalysis of Heterocyclic Azadiene Cycloaddition Reactions by Solvent Hydrogen Bonding: Concise Total Synthesis of Methoxatin [J] . Christopher M. Glinkerman, Dale L. Boger Journal of the American Chemical Society . 2016,第38期

机译：溶剂氢键催化杂环氮杂二烯环加成反应：甲基异莫司汀的全合成
3. Inverse Electron Demand Diels-Alder Reactions of Heterocyclic Azadienes, 1-Aza-1,3-Butadienes, Cyclopropenone Ketals, and Related Systems. A Retrospective [J] . Zhang Jiajun, Shukla Vyom, Boger Dale L. The Journal of Organic Chemistry . 2019,第15期

机译：逆电子需求Diels-杂环酰胺，1-AZA-1,3-丁二烯，环烯酮酮和相关系统的反应。回顾一下
4. Tandem Diels-Alder Reactions of Arynes: New Method for the Synthesis of Large Poly cyclic Aromatic Compounds and Nanographenes [C] . Diego Pena, Alejandro Criado, Dolores Perez European Symposium on Organic Chemistry . 2009

机译：Arynes的串联Diels-Alder反应：用于合成大聚环芳族化合物和纳米的新方法
5. Part I. Applications of inverse electron demand Diels-Alder reactions of heterocyclic azadienes: Two syntheses of Amaryllidaceae alkaloids. Part II. In situ activation of a DNA alkylating agent: Evaluation of simplified and reversed CPyI analogues of CC-1065 and the duocarmycins. Part III. Progress toward the total synthesis of cytostatin. [D] . Wolkenberg, Scott Evan. 2003

机译：第一部分。逆向电子需量的应用杂环氮杂二烯的Diels-Alder反应：金莲花科生物碱的两种合成。第二部分DNA烷化剂的原位活化：评估CC-1065和Duocarmycins的简化和反向CPyI类似物。第三部分向细胞抑制素的全合成方向发展。
6. Catalysis of Heterocyclic Azadiene Cycloaddition Reactions by Solvent Hydrogen Bonding: Concise Total Synthesis of Methoxatin [O] . Christopher M. Glinkerman, Dale L. Boger -1

机译：溶剂氢键催化杂环氮杂二烯环加成反应：甲氧沙丁啶的全合成
7. Catalysis of Heterocyclic Azadiene Cycloaddition Reactions by Solvent Hydrogen Bonding: Concise Total Synthesis of Methoxatin [O] . -1

机译：溶剂氢键合杂环氮苯二烯环加成反应的催化作用：简化总合成甲氧嘧啶
8. Nucleophilic Substitution Reactions of Heterocyclic Amines and Acyclic Diamineswith Chlorofluoroolefins and Hexafluoropropylene Oxide [R] . Mir, Q. C., Guo, C. Y., Kirchmeier, R. L., 1994

机译：杂环胺和无环二胺与氯氟烯烃和六氟环氧丙烷的亲核取代反应

Heterocyclic and acyclic azadiene Diels-Alder reactions: Total synthesis of nothapodytine B

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