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Fluctuation interactions of colloidal particles

机译:胶体颗粒的波动相互作用

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摘要

For like-charged colloidal particles, two mechanisms of attraction between them survive when the interparticle distance is larger than the Debye screening length. One of them is the conventional van der Waals attraction and the second is the attraction mechanism mediated by thermal fluctuations of particle position. The latter is related to the effective variable mass (Euler mass) of the particles produced by the fluid motion. The strongest attraction potential (up to the value of the temperature T) corresponds to the case of uncharged particles and a relatively large Debye screening length. In this case, the third attraction mechanism is involved. It is mediated by thermal fluctuations of the fluid density.
机译:对于带相同电荷的胶体粒子,当粒子间距离大于Debye筛选长度时,它们之间的两种吸引力机制得以保留。其中之一是传统的范德华吸引力,第二是由颗粒位置的热波动介导的吸引力机制。后者与流体运动产生的颗粒的有效可变质量(欧拉质量)有关。最强的吸引力(达到温度T的值)对应于不带电粒子和相对较大的德拜筛分长度的情况。在这种情况下,涉及第三吸引机制。它是由流体密度的热波动来调节的。

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