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首页> 外文期刊>Journal of Experimental and Theoretical Physics >Laser control of low-temperature reaction e - + O _2~+
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Laser control of low-temperature reaction e - + O _2~+

机译:激光控制低温反应e-+ O _2〜+

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摘要

A theory is developed to describe dissociative recombination of a slow electron with a ground-state molecular ion of oxygen driven by a strong monochromatic electromagnetic field. Mathematically, the theory is based on the time-independent formalism of radiative scattering matrix whose poles correspond to dressed intermediate states of the complex. The analysis embraces both transitions to dissociative states and laserinduced nonadiabatic transitions to intermediate bound states of valence configurations. Key reaction mechanisms are considered, and a classification is given of all allowed transitions to dissociative states. Partial and total reaction cross sections are calculated by taking into account the contributions from Rydberg, valence, and dissociative states of O _2** . A detailed discussion of results is presented, and feasibility of laser control of the reaction is demonstrated.
机译:发展了一种理论来描述慢电子与由强单色电磁场驱动的氧的基态分子离子的解离复合。在数学上,该理论基于辐射散射矩阵的时间独立形式,该辐射散射矩阵的极点对应于复合体的整齐中间状态。该分析既包含向离解态的跃迁,也包括激光诱导的非绝热跃迁至价构型的中间束缚态。考虑了关键的反应机理,并给出了所有允许的离解态转变的分类。通过考虑Rydberg的贡献,化合价和O _2 **的解离态来计算部分和全部反应截面。给出了结果的详细讨论,并证明了激光控制反应的可行性。

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