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Mechanical properties of styrene butadiene rubber-/ethylene propylene diene monomer rubber-based conductive blends

机译:苯乙烯丁二烯橡胶/乙烯丙烯二烯单体橡胶基导电混合物的机械性能

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摘要

The mechanical properties of styrene butadiene rubber (SBR)/ethylene propylene diene monomer rubber (EPDM) conductive blends prepared by conventional mixed method were studied as a function of both blend ratio and high-abrasion furnace (HAF) carbon black (CB) contents. All measured mechanical characteristics, such as Young's modulus, strain at break and stress at break, exhibit a transition at percolation threshold (Φ_C), which was found to be dependent on the SBR/EPDM blend ratio. From the dependence of the electrical conductivity of SBR, EPDM and their blends filled with HAF CB on the volume portion of the filler, the percolation concentration (Φ_c) was determined to be at the inflexion point Φ_i of the dependency. The elongation at break of the investigated composites was succeeded to connect to the percolation concentration by Novak et al. model and an empirical formula suggested by us and showed reasonable results.
机译:研究了通过常规混合方法制备的丁苯橡胶(SBR)/乙丙二烯单体橡胶(EPDM)导电共混物的机械性能随共混比和高磨损炉(HAF)炭黑(CB)含量的变化。所有测得的机械特性(例如杨氏模量,断裂应变和断裂应力)均在渗流阈值(Φ_C)处发生转变,这取决于SBR / EPDM共混比。根据SBR,EPDM及其填充有HAF CB的共混物的电导率对填料体积部分的依赖性,可以确定渗滤浓度(Φ_c)处于依赖性的拐点Φ_i。 Novak等人成功地将所研究复合材料的断裂伸长率与渗滤浓度联系起来。我们提出的模型和经验公式表明了合理的结果。

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