An in-situ infrared spectroscopic study of the adsorption of citrate on Au(lll) electrodes

Simon Floate; Mirghasem Hosseini; Mohammad R. Arshadi; David Ritson; Karen L. Yong; Richard J. Nichols

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An in-situ infrared spectroscopic study of the adsorption of citrate on Au(lll) electrodes

机译：柠檬酸盐在Au（III）电极上的吸附的原位红外光谱研究

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The specific adsorption of citrate from perchloric acid electrolytes, has been investigated using in-situ FTIR spectroscopy at Au(lll) electrodes. For comparison IR spectra for formate adsorption are also presented. Clear voltammetric peaks have been observed positive of the pzc and these are shown by FTIR spectroscopy to be associated with the adsorption of citrate. Models for the surface co-ordination of the citrate anion are discussed.

机译：使用原位FTIR光谱在Au（III）电极上研究了高氯酸电解质对柠檬酸的特定吸附。为了比较，还给出了甲酸吸附的红外光谱。已观察到pzc呈阳性的清晰伏安峰，并且FTIR光谱表明这些峰与柠檬酸盐的吸附有关。讨论了柠檬酸根阴离子的表面配位模型。

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《Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry》 |2003年第0期|共8页
作者
Simon Floate; Mirghasem Hosseini; Mohammad R. Arshadi; David Ritson; Karen L. Yong; Richard J. Nichols;
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正文语种 eng
中图分类分析化学;
关键词
infrared spectroscopy; citric acid; citrate; Au(lll); FTIR;

机译：红外光谱;柠檬酸;柠檬酸盐;Au（III）;FTIR;

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1. An in-situ infrared spectroscopic study of the adsorption of citrate on Au(lll) electrodes [J] . Simon Floate, Mirghasem Hosseini, Mohammad R. Arshadi, Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 2003,第0期

机译：柠檬酸盐在Au（III）电极上的吸附的原位红外光谱研究
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An in-situ infrared spectroscopic study of the adsorption of citrate on Au(lll) electrodes

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