Electrodeposition method for controlled formation of CdS films from aqueous solutions

摘要

Polycrystalline CdS films of good quality could be obtained by electrolysis with rectangular voltages on indium tin oxide/glass substrates from low concentration of CdSO_4 and Na_2S_2O_3 in aqueous solution system of pH 3.1 at room temperature (r.t.). The films obtained during 6 s at -1.0 V (versus Ag|AgCl|3 M NaCl) and 6 s at 0.0 V gave stoichiometric CdS with a hexagonal polycrystalline structure with a preferred a-axis orientation. It is suggested that the mass transfer of Cd~(2+) to the substrate surface governs the deposition rate of CdS. The film deposited at 6 s of -1.2 V and 6 s of 0.0 V gave a c-axis preferred orientation. Incorporation of S into the films was affected by the applied potential, and the reduction of S controls the deposition reaction.