FABRICATION OF MULTILAYER FILMS CONTAINING 1/12 PHOSPHOMOLYBDIC ANIONS ON THE SURFACE OF A GOLD ELECTRODE BASED ON ELECTROSTATIC INTERACTION AND ITS APPLICATION AS AN ELECTROCHEMICAL DETECTOR IN FLOW-INJECTION AMPEROMETRIC DETECTION OF HYDROGEN PEROX

摘要

Novel multilayer films containing 1:12 phosphomolybdic anions were achieved on the surface of a gold electrode by alternating deposition of 1:12 phosphomolybdic anion with water-soluble polypyrrole. The chemically-modified electrode (CME) was shown to exhibit an electrocatalytic response for the reduction of hydrogen peroxide. Hydrogen peroxide was detected by flow-injection analysis at the modified electrode with high sensitivity. The method gave a linear range from 1 X 10(-2) moll(-1) to 1 X 10(-5) moll(-1) and a detection limit of 1 X 10(-6) moll(-1) (signal-to-noise ratio 3). (C) 1997 Elsevier Science S.A. [References: 19]