POST-POLYMERIZATION ELECTROCHEMICAL FUNCTIONALIZATION OF A CONDUCTING POLYMER - ANODIC CYANATION OF POLY(P-DIMETHOXYBENZENE)

Fabre B.; Simonet J.

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POST-POLYMERIZATION ELECTROCHEMICAL FUNCTIONALIZATION OF A CONDUCTING POLYMER - ANODIC CYANATION OF POLY(P-DIMETHOXYBENZENE)

机译：导电聚合物的后聚合电化学功能-聚（对二甲氧基苯）的阳极氧化

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Anodic cyanation reactions of electroformed poly(p-dimethoxybenzene) and co[poly(p-dimethoxybenzene)+poly(3-methylthiophene)] films can be performed in CH3CN+0.2M NEt(4)CN at 1.2+/-0.1 V (vs. 10(-1) M Ag+/Ag). The electrochemical replacement of the aromatic methoxy group by nitrile is mainly supported by IR measurements (specific band nu(CN) at around 2200 cm(-1)). [References: 11]

机译：可以在CH3CN + 0.2M NEt（4）CN上于1.2 +/- 0.1 V（CH3CN + 0.2M NEt（4）CN进行电铸聚（对二甲氧基苯）和共聚（对二甲氧基苯）+聚（3-甲基噻吩）薄膜的阳极氰化反应（ vs.10（-1）M Ag + / Ag）。红外测量主要是通过腈的电化学取代芳族甲氧基取代（在2200 cm（-1）左右的特定谱带nu（CN））。 [参考：11]

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《Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry》 |1996年第2期|共3页
作者
Fabre B.; Simonet J.;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;分析化学;
关键词
Cyanation; Electronic conducting polymer; Poly(p-dimethoxybenzene); Poly(3-methylthiophene); Oxidation;

机译：氰化;电子导电聚合物;聚对二甲氧基苯;聚3-甲基噻吩;氧化;

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1. POST-POLYMERIZATION ELECTROCHEMICAL FUNCTIONALIZATION OF A CONDUCTING POLYMER - ANODIC CYANATION OF POLY(P-DIMETHOXYBENZENE) [J] . Fabre B., Simonet J. Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 1996,第1a2期

机译：导电聚合物的后聚合电化学功能-聚（对二甲氧基苯）的阳极氧化
2. Efficient post-polymerization functionalization of conducting poly(3,4-ethylenedioxythiophene) (PEDOT) via 'click'-reaction [J] . Bu H.-B., G?tz G., Reinold E., Tetrahedron . 2011,第6期

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5. End-group functionalization of regioregular head-to-tail poly(3-alkylthiophenes) and its application to the synthesis of well-defined rod-coil block copolymers: Tuning the self-assembly and functional properties of conducting polymers. [D] . Liu, Jinsong. 2002

机译：区域规则的头对尾聚（3-烷基噻吩）的端基官能化及其在合成明确的棒-线圈嵌段共聚物中的应用：调节导电聚合物的自组装和功能特性。
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机译：二茂铁功能化的4-（25-二（噻吩-2-基）-1H-吡咯-1-基）苯胺：基于聚合物的电化学生物传感器的新型设计
7. Post-polymerization functionalization of poly(ethylene oxide)–poly(β-6-heptenolactone) diblock copolymers to tune properties and self-assembly [O] . Brooke M. Raycraft, Jarret P. MacDonald, James T. McIntosh, 2017

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POST-POLYMERIZATION ELECTROCHEMICAL FUNCTIONALIZATION OF A CONDUCTING POLYMER - ANODIC CYANATION OF POLY(P-DIMETHOXYBENZENE)

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