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首页> 外文期刊>Journal of Dispersion Science and Technology >A free energy model for curved surfaces and curved thin films in emulsions
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A free energy model for curved surfaces and curved thin films in emulsions

机译:乳液中曲面和曲面薄膜的自由能模型

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The formulation of surface thermodynamics for flat surfaces has been done so as to be free of the Gibbs surface construction. The advantage of these formulations is that it allows the choice of thermodynamic field variables that is more general than the traditional construction. However a generalization to curved surfaces including thin films that exist in emulsion structures has not been published. The Hansen-Cahn construction is developed in a setting that allows curvature terms to be added to the free energy expression. The Laplace equation extended to include bending elasticity and spontaneous bending elasticity is derived by computing functional derivatives of the free energy. Results for both single interfaces and double interfaces are reported. Stability conditions for profile fluctuations are developed to include these additional properties. [References: 17]
机译:已经完成了用于平坦表面的表面热力学的公式化,从而没有吉布斯表面构造。这些公式的优点在于,它允许选择比传统结构更通用的热力学场变量。然而,尚未公开对包含存在于乳液结构中的薄膜的曲面的概括。 Hansen-Cahn结构的开发环境允许将曲率项添加到自由能表达式中。拉普拉斯方程扩展为包括弯曲弹性和自发弯曲弹性,是通过计算自由能的函数导数得出的。报告单接口和双接口的结果。开发了轮廓波动的稳定性条件以包括这些附加属性。 [参考:17]

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