Synthesis and characterization of bis(diphenylphosphino) acetylene bridged binuclear platinum(II) complexes with terminal organochalcogenide groups. X-ray crystal structure of [pt_2(sc_6f_5)_4(#mu#-ph_2pcident to cpph_2)_2]

Anshu Singhal; Vimal K.Jain

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Synthesis and characterization of bis(diphenylphosphino) acetylene bridged binuclear platinum(II) complexes with terminal organochalcogenide groups. X-ray crystal structure of [pt_2(sc_6f_5)_4(#mu#-ph_2pcident to cpph_2)_2]

机译：具有末端有机硫属化物基团的双（二苯基膦基）乙炔桥联的双核铂（II）配合物的合成和表征。 [pt_2（sc_6f_5）_4（＃mu＃-ph_2入射到cpph_2）_2]的X射线晶体结构

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Binuclear platinum(II) complexes of the type[pt_2(sc_6f_5)_4(#mu#-ph_2pcident to cpph_2)_2] (ER=SPr~i,Sbu~i, SPh, SC_6H_4CI-4,SC_6F_5, SePh) have been preparedand characterized by elemental analysis and NMR spectroscopy. Asingle-crystal x-ray structure determination of[pt_2(sc_6f_5)_4(#mu#-ph_2pcident to cpph_2)_2] hasestablished the binuclear formulation with terminal thiolatogroups. The platinum atoms lie in a distorted square planarenvironment with the sulfur and the phosphine ligands arranged in a cis fashion.

机译：制备了类型为[pt_2（sc_6f_5）_4（＃mu＃-ph_2pccpcp_2）_2的双核铂（II）配合物（ER = SPr〜i，Sbu〜i，SPh，SC_6H_4CI-4，SC_6F_5，SePh）通过元素分析和NMR光谱表征。 [pt_2（sc_6f_5）_4（＃mu＃-ph_2与cpph_2）_2的单晶X射线结构测定已建立了具有末端硫醇基的双核制剂。铂原子处于扭曲的正方形平面环境中，硫和膦配体以顺式排列。

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《Journal of Coordination Chemistry》 |1999年第3期|共9页
作者
Anshu Singhal; Vimal K.Jain;
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正文语种 eng
中图分类无机化学;
关键词
platinum; synthesis; NMR; X-ray structure;

机译：铂;合成;NMR;X射线结构;

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1. Synthesis and characterization of bis(diphenylphosphino) acetylene bridged binuclear platinum(II) complexes with terminal organochalcogenide groups. X-ray crystal structure of [pt_2(sc_6f_5)_4(#mu#-ph_2pcident to cpph_2)_2] [J] . Anshu Singhal, Vimal K.Jain Journal of Coordination Chemistry . 1999,第3期

机译：具有末端有机硫属化物基团的双（二苯基膦基）乙炔桥联的双核铂（II）配合物的合成和表征。 [pt_2（sc_6f_5）_4（＃mu＃-ph_2入射到cpph_2）_2]的X射线晶体结构
2. Binuclear organoplatinum(II) complexes with double bis(diphenylphosphino) acetylene bridges: Synthesis, X-ray structure determination, electronic structures and DFT calculations [J] . Nabavizadeh S. Masoud, Sepehrpour Hajar, Jamshidi Mahboubeh, Journal of Organometallic Chemistry . 2016,第Null期

机译：双双（二苯基膦基）乙炔桥双核有机铂（II）配合物：合成，X射线结构测定，电子结构和DFT计算
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机译：烷基氨基双（二氟膦）双核钼羰基配合物中对称和不对称桥联羰基;两种配合物的X射线晶体结构

Synthesis and characterization of bis(diphenylphosphino) acetylene bridged binuclear platinum(II) complexes with terminal organochalcogenide groups. X-ray crystal structure of [pt_2(sc_6f_5)_4(#mu#-ph_2pcident to cpph_2)_2]

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