Tuning the pi-backbonding and sigma-trans effect of (NCN)-C-boolean AND-N-boolean AND coordinated Pt(II) complexes. Kinetic and computational study

Papo Tshephiso R.; Jaganyi Deogratius

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Tuning the pi-backbonding and sigma-trans effect of (NCN)-C-boolean AND-N-boolean AND coordinated Pt(II) complexes. Kinetic and computational study

机译：调整（NCN）-C-布尔AND-N-布尔AND配位的Pt（II）配合物的pi背键和sigma反式效应。动力学和计算研究

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摘要

The mechanistic pathway for the substitution reaction of a strong trans labilizing phenyl of N boolean AND C boolean AND N platinum(II) complexes by biorelevant thiourea nucleophiles go through the solvent associated pathway.

机译：生物相关的硫脲亲核试剂对N布尔与C布尔与N铂（II）配合物的强反式通透性苯基的取代反应的机理途径通过溶剂相关途径。

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《Journal of Coordination Chemistry》 |2015年第6期|共14页
作者
Papo Tshephiso R.; Jaganyi Deogratius;
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正文语种 eng
中图分类无机化学;
关键词
Kinetics; Mechanistic; Platinum; Substitution;

机译：动力学;力学;白金;替代;

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1. Tuning the pi-backbonding and sigma-trans effect of (NCN)-C-boolean AND-N-boolean AND coordinated Pt(II) complexes. Kinetic and computational study [J] . Papo Tshephiso R., Jaganyi Deogratius Journal of Coordination Chemistry . 2015,第5a6期

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Tuning the pi-backbonding and sigma-trans effect of (NCN)-C-boolean AND-N-boolean AND coordinated Pt(II) complexes. Kinetic and computational study

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