Syntheses, crystal structures, and properties of four transition metal complexes based on 5-nitro-8-hydroxyquinoline

摘要

Four new complexes, [M(C_9H_5N_2O_3)_2(H_2O)_2]CH_3OH (M = Zn(II), Cd(II) and Mn(II)) (1-3) and [Cu(C_9H_5N_2O_3)_2] (4), have been synthesized by reactions of 5-nitro-quinoline-8-yl acetate (NQA) and corresponding metal salts at room temperature and characterized by elemental analysis, 1R, thermal gravimetric analysis (TGA), fluorescence measurement and single crystal X-ray diffraction. 1-3 are mononuclear, further extended to 2-D layers by hydrogen bonds. For 4, Cu~(2+) is coordinated by two N atoms and two O atoms from two NQ ligands. TGA indicates that 1-4 have good thermal stabilities. Furthermore, 1 and 2 show excellent luminescence in the solid state at room temperature.