A new Zn~(II) two-dimensional coordination polymer, {[Zn(mu-4,4'-bipy)(l,4-ndc)(H_2O)_2].(H_2O)}_n (4,4'-bipy =4,4'-bipyridine and l,4-ndc = l,4-naphthalenedicarboxylate)

摘要

A 2D Zn~(II)(mu-4,4'-bipy) coordination polymer with 1,4-naphthalenedicarboxylate, {[Zn(mu-4,4'-bipy)(l,4-ndc)(H_2O)_2]-(H_2O)}_n, has been synthesized, characterized and studied by X-ray crystallography. The structural studies show the Zn atoms have six-coordinate geometry with a distorted octahedral environment. The 2D structure is grown by hydrogen bonds into a hybrid three-dimensional network.