Syntheses, structures and characterization of the tetranuclear tin(IV) oxysulfide clusters (n-Bu_4N)_2[Sn_4(mu_4-O)S_5(edt)_2X_2] (X = Cl, Br) (edt = 1,2-ethanedithiolate)

LONG-SHENG WANG; TIAN-LU SHENG; JIAN-JUN ZHANG

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Syntheses, structures and characterization of the tetranuclear tin(IV) oxysulfide clusters (n-Bu_4N)_2[Sn_4(mu_4-O)S_5(edt)_2X_2] (X = Cl, Br) (edt = 1,2-ethanedithiolate)

机译：四核氧硫化锡（IV）簇（n-Bu_4N）_2 [Sn_4（mu_4-O）S_5（edt）_2X_2]（X = Cl，Br）（edt = 1,2-乙二硫醇盐）的合成，结构和表征

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During attempts to prepare cubane-like clusters from the precursor (Bu_4N)_2[Sn_3S_4(edt)_3] (edt = 1,2-ethanedithiolate), two new tetranuclear tin(IV) oxysulfide clusters, (Bu_4N)_2 [Sn_4(mu_4-O)S_5(edt)_2Cl_2] (1) and (Bu_4N)_2[Sn_4(mu_4-O)S_5(edt)_2Br_2] (2) were unexpectedly obtained by reaction of (Bu_4N)_2[Sn_3S_4(edt)_3] with SnX_2 (X = Cl, Br). X-ray crystal structure analyses show that the two compounds possess an isostructural anionic cluster with a highly distorted tetrahedral metal skeleton. The two compounds have been characterized spectroscopically.

机译：在尝试从前体（Bu_4N）_2 [Sn_3S_4（edt）_3]（edt = 1,2-乙烷二硫代硫酸盐）制备古巴样簇的过程中，两个新的四核氧化硫锡（IV）簇（Bu_4N）_2 [Sn_4（mu_4） -O）S_5（edt）_2Cl_2]（1）和（Bu_4N）_2 [Sn_4（mu_4-O）S_5（edt）_2Br_2]（2）通过（Bu_4N）_2 [Sn_3S_4（edt）_3]的反应意外获得SnX_2（X = Cl，Br）。 X射线晶体结构分析表明，这两种化合物具有同构型阴离子簇，具有高度扭曲的四面体金属骨架。两种化合物已通过光谱表征。

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《Journal of Coordination Chemistry》 |2008年第17期|共8页
作者
LONG-SHENG WANG; TIAN-LU SHENG; JIAN-JUN ZHANG;
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正文语种 eng
中图分类无机化学;
关键词
Cluster; Crystal structure; Tin; Sulfur; Oxysulfide; Spectroscopy;

机译：团簇;晶体结构;锡;硫;氧硫化物;光谱学;

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Syntheses, structures and characterization of the tetranuclear tin(IV) oxysulfide clusters (n-Bu_4N)_2[Sn_4(mu_4-O)S_5(edt)_2X_2] (X = Cl, Br) (edt = 1,2-ethanedithiolate)

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