Hydrothermal synthesis and crystal structure of a metal-organic compound with unique pseudo-hexagonal water channels: [Cu~(II)(phen)(sal)] centre dot 0.5H_2O (phen = 1,10-phenanthroline, sal = salicylic acid)

DEXIN HU; FENG LUO; JIMIN ZHENG

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Hydrothermal synthesis and crystal structure of a metal-organic compound with unique pseudo-hexagonal water channels: [Cu~(II)(phen)(sal)] centre dot 0.5H_2O (phen = 1,10-phenanthroline, sal = salicylic acid)

机译：具有独特拟六方水通道的金属有机化合物的水热合成和晶体结构：[Cu〜（II）（phen）（sal）]中心点0.5H_2O（phen = 1,10-菲咯啉，sal =水杨酸）

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This article presents a metal-organic compound [Cu~(II)(phen)(sal)] centre dot 0.5H_2O (1) with intriguing structural motif of 3D hexagonal water channels. Furthermore, IR, element analysis, and TGA were employed to characterize it. The TG-DTA showed that this structure is stable to 300 deg C. Compound 1 belongs to the hexagonal system, space group R-3, a = 33.337(5) A, b = 33.337(5) A, c = 9.4599(19) A, gamma =120 deg, V = 9105(3) A~3, Z = 18.

机译：本文提出了一种金属有机化合物[Cu〜（II）（phen）（sal）]中心点0.5H_2O（1），它具有3D六角形水通道的有趣结构图案。此外，采用红外光谱，元素分析和TGA对其进行表征。 TG-DTA表明该结构在300摄氏度下稳定。化合物1属于六边形体系，空间群R-3，a = 33.337（5）A，b = 33.337（5）A，c = 9.4599（19））A，伽玛= 120度，V = 9105（3）A〜3，Z = 18。

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《Journal of Coordination Chemistry》 |2007年第11期|共7页
作者
DEXIN HU; FENG LUO; JIMIN ZHENG;
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正文语种 eng
中图分类无机化学;
关键词
1; 10-Phenanthroline; Salicylic acid; Water channel; Porous materials;

机译：1;10-菲咯啉;水杨酸;水通道;多孔材料;

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1. Hydrothermal synthesis and crystal structure of a metal-organic compound with unique pseudo-hexagonal water channels: [Cu~(II)(phen)(sal)] centre dot 0.5H_2O (phen = 1,10-phenanthroline, sal = salicylic acid) [J] . DEXIN HU, FENG LUO, JIMIN ZHENG Journal of Coordination Chemistry . 2007,第10a11期

机译：具有独特拟六方水通道的金属有机化合物的水热合成和晶体结构：[Cu〜（II）（phen）（sal）]中心点0.5H_2O（phen = 1,10-菲咯啉，sal =水杨酸）
2. Co-operation of pi center dot center dot center dot pi, Cu(II)center dot center dot center dot pi, carbonyl center dot center dot center dot pi and hydrogen-bonding forces leading to the formation of water cluster mimics observed in the reassessed crystal structure of [Cu(mal)(phen)(H2O)]2 center dot 3H(2)O (H(2)mal = malonic acid, phen=1,10-phenanthroline) [J] . Choudhury SR, Lee HM, Hsiao TH, Journal of Molecular Structure . 2010,第1a3期

机译：pi中心点中心点中心点pi，Cu（II）中心点中心点中心点pi，羰基中心点中心点中心点pi和氢键合力导致重新评估时观察到的水簇模拟物的形成[Cu（mal）（phen）（H2O）] 2中心点3H（2）O的晶体结构（H（2）mal =丙二酸，phen = 1,10-菲咯啉）
3. A new B-Anderson-type heteropoly compound containing binuclear copper(II) coordination Ions: synthesis, molecular structure and properties of [Cu_2(phen)_2(CH_3COO)_2(H_2O)_2] [HAl(OH)_6(Mo_6O_(18))] centre dot 2.5H_2O (phen = 1,10-phenanthroline) [J] . JING-PING WANG, JUN-WEI ZHAO, SU-ZHI LI Journal of Coordination Chemistry . 2006,第6期

机译：含双核铜（II）配位离子的新型B-Anderson型杂多化合物：[Cu_2（phen）_2（CH_3COO）_2（H_2O）_2] [HAl（OH）_6（Mo_6O_（18）））]中心点2.5H_2O（phen = 1,10-菲咯啉）
4. Hydrothermal Synthesis and Characterization of the Coordination Polymers with bta =Benzene-1,2,4,5- tetracarboxylate as Bridging Ligand: {Cu(phen)(μ4-bta)1/2· (H2O)}n(phen= 1,10-phenanthroline) [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：以bta =苯-1,2,4,5-四羧酸苯酯为桥联配体的水热合成和表征：{Cu（phen）（μ4-bta）1/2·（H2O）} n（phen = 1,10-菲咯啉
5. Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of Mn(ph)(Phen)2(H2O)· 4H2O Mn(Phen)2(H2O)22(Isoph)2(Phen)· 12H2O and {Mn(Isoph)(bipy)4· 2.75biby}n(phH2 = Phthalic Acid; isoph = Isophthalic Acid; phen = 110-Phenanthroline; bipy = 22-Bipyridine) [O] . Michael Devereux, Malachy McCann, Vanessa Leon, 2000

机译：邻苯二甲酸和间苯二甲酸锰（II）配合物的合成和生物活性：Mn（ph）（Phen）2（H2O）·4H2OMn（Phen）2（H2O）2 2的X射线晶体结构（Isoph）2（Phen）·12H2O和{Mn（Isoph）（bipy） 4·2.75biby} n（phH2 =邻苯二甲酸; isoph =间苯二甲酸; phen = 110-邻菲咯啉; bipy = 22 -联吡啶）
6. Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of [Mn(ph)(Phen)2(H2O)]· 4H2O, [Mn(Phen)2(H2O)2]2(Isoph)2(Phen)· 12H2O and {[Mn(Isoph)(bipy)]4· 2.75biby}n(phH2 = Phthalic Acid; isoph = Isophthalic Acid; phen = 1,10-Phenanthroline; bipy = 2,2-Bipyridine) [O] . Devereux, Michael, McCann, Malachy, Leon, Vanessa, 2000

机译：邻苯二甲酸和间苯二甲酸锰（II）配合物的合成和生物活性：[Mn（ph）（Phen）2（H2O）]·4H2O，[Mn（Phen）2（H2O）2] 2的X射线晶体结构（Isoph）2（Phen）·12H2O和{[Mn（Isoph）（bipy）] 4·2.75biby} n（phH2 =邻苯二甲酸; isoph =间苯二甲酸; phen = 1,10-邻菲咯啉; bipy = 2,2 -联吡啶）

Hydrothermal synthesis and crystal structure of a metal-organic compound with unique pseudo-hexagonal water channels: [Cu~(II)(phen)(sal)] centre dot 0.5H_2O (phen = 1,10-phenanthroline, sal = salicylic acid)

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