Nature of Spilt-over Hydrogen on Acid Sites in Zeolites: Observation of the Behavior of Adsorbed Pyridine on Zeolite Catalysts by Means of FTIR

摘要

The effect of spilt-over hydorgen on catalysts which were prepared by physically mixing zeolites or alumina with SiO_2-supported noble metals on chemisorbed pyridine was inestigated by means of FTIR and TPD. It has been found that pyridine adsorbed on a Lewis acid site migrated to a Bronsted acid site under a hydrogen atmosphere. This suggests that spilt-over hydorgen should enhance the desorption of pyridine on the Lewis acid site, and that the possible state of spilt-over hydrogen on the Lewis acid site should be hydride, which has strong Lewis basicity. Furthermore, H-D exchange (-OH + D_2) of the Bronsted acid site was also carried out which leads to a complete description of interactions between spilt-over hydrogen and sites of zeolite.