Exchange characteristics of monocarboxylic acids and monosulfonic acids onto anion-exchange resins

摘要

In the previous paper (N.Kanazawa,K.Urano,N.Kokado,Y.Urushigawa,J.Colloid Sci.238 (2001) 196),the equilibria of propionic acid and benzoic acid adsorption onto three anion-exchange resins were investigated,and an equation was proposed that summed of the physical adsorption of the carboxylic acid molecule and the ion exchange of the dissociated carboxylate ion.The ion exchange equation,including a selectivity coefficient to chloride ion for each combination between carboxylate ions and anion-exchange resins,could be used in wide ranges of concentration and pH.In this research,ion-exchange equilibria using 16 anion-exchange resins and 9 organic acids including monocarboxylic and monosulfonic acids were investigated.It could be onfirmed that the proposed equation applied to the ion exchange with those monoorganic acids.Characteristics of ion exchange between the organic anions and anion exchnge were also studied by the selectivity coefficients.