Reactions of bis(N-phenylsalicylidene iminato)aluminium-di-mu-isopropoxo-di-isopropoxo aluminium(III) with glycols

摘要

Reactions of bis(N-phenylsalicylidene iminato)aluminium-di-mu-isopropoxo-di-isopropoxo aluminium(III), [C6H4O{CH=N(C6H5))](2)Al(mu-OPri)(2)Al(OPri)(2) with glycols in 1:1 molar ratio in refluxing anhydrous benzene yielded binuclear complexes of the type, [C6H4O{CH=N(C6H5)}](2)Al(mu-OPri)(2)Al(O-G-O) [where G = (CH2)(2) CH2CH(CH3), CH2CH(C2H5), CH(CH3)CH(CH3), (CH2)(5), C(CH3)(2)CH2CH(CH3), (CH2)(6)], respectively. All these binuclear complexes have been characterised by elemental analysis, molecular weight measurements and spectroscopic(IR and NMR) studies. [References: 14]