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Chemical analysis of white porcelains from the Ding Kiln site, Hebei Province, China

机译:中国河北省鼎窑遗址的白瓷的化学分析

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The Ding kilns were some of the most famous early kilns of medieval China, producing huge quantities of white and cream-white porcelains of outstanding technical and aesthetic quality. Since 1949 they have been excavated three times, in 1965, in 1987, and in 2009 respectively. In this latest study 69 white porcelain sherds from assured contexts and from the 2009 excavations were analyzed using laser ablation techniques (ICP-AES). The samples date from Five Dynasties, Northern Song and Jin Dynasties respectively (early 10~(th) to early 13~(th) C CE). The results show that Ding wares of different times show different characteristics that can be demonstrated through chemical composition. During the early phase of production the Ding ware bodies consisted largely of high firing kaolinitic clays with predominantly calcareous materials as fluxes. After the early Northern Song Dynasty, some calcareous material was replaced by a more potassic material. The compositions of the glazes show a parallel evolution to the bodies. However, because the glazes are very low in titania it seems unlikely that the main clay ingredients of the bodies could have been used in the glaze recipes. For much of the kiln site’s history the glazes appear to have been made mainly from the same siliceous flux-rich materials that had been blended with the main body-clays used to make the Ding ware porcelains, plus some extra calcareous material. The P_2O_5 contents of the glazes suggest that wood ash may have been one source of CaO in the glaze recipes.
机译:鼎窑是中世纪中国最著名的早期窑炉,生产大量技术和美学品质卓著的白色和米白色瓷器。自1949年以来,分别在1965年,1987年和2009年对它们进行了三次挖掘。在这项最新研究中,使用激光烧蚀技术(ICP-AES)分析了来自可靠环境和2009年发掘的69个白色瓷片。样本分别来自北宋和金五朝(公元10世纪初至13世纪初)。结果表明,不同时期的丁器具有不同的特征,可以通过化学成分证明。在生产的早期阶段,Ding器体主要由高烧高岭土组成,主要以钙质材料为助熔剂。北宋初期之后,一些钙质物质被更钾质的物质所取代。釉的成分显示出与物体平行的演变。但是,由于釉料中的二氧化钛含量非常低,因此似乎不太可能在釉料配方中使用主体的主要粘土成分。在窑址的大部分历史中,釉料似乎主要是由富含硅质助熔剂的材料制成的,这些材料与用于制作丁瓷器的主体粘土混合,再加上一些钙质材料。釉料中P_2O_5的含量表明,木灰可能是釉料配方中CaO的一种来源。

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