The Reactions of 2-(4-Morpholinothio) - and 2- (4-Morpholinodithio) Benzothiazole in the Absence of Polyisoprene

摘要

2-(4-morpholinothio)benxothiazole (MOR) and 2-(4-morpholinodithio) benzothiazoe (MDB) were heated with sulfur and ZnO in a DSC. The products formed at various temepratures were identified and analyzed by HPLC. At temperatures below 200deg C, decomposition of the accelerator in the absence of other curatives was slow, degradatio products being mainly 2-bisbenzothiazole-2,2'-disulfide (MBTS) and 2- mereaptobenzothiazoel MBT (or its amine salt) and 2-(4-morpholino)benzothiazole (MB). MOR and MDB reacted with sulfur to form higher polysulfides. MDB was shown to react more readily iwth sulfur than MOR and the delayed action of MOR in rubber can therefore not be ascribed to a stable polysulfide as suggested by other authors. Neither MOR nor MDB was found to react with ZnO. A limited reaction between MBT and ZnO was observed.