Acrylonitrile Copolymers: Synthesis, Characterization, and Formation of Ultrafiltration Membranes

摘要

A variety of poly(acrylonitrile-co-acrylamide) polymers of different compositions were synthesized by free radical copolymerization. Thin films were cast from polymer solutions, and coagulated into ultrafiltration membranes. The effect of preparative parameters on membrane gel structure was investigated. For nonsupported membranes, concentrated solutions produce fine pore membranes with a lower flux; extending the drying causes a diminution in membrane thickness, swelling index, and fluxes; the membrane thickness, swelling index, and premate flux all increased with increasing coagulation bath temperature. For supported membranes, dilute polymer casting solutions, small casting gate opening, and added polyvinylpyrrolidone to the casting solution all increased the permeate flux. The membranes containing acrylamide were more hydrophilic, and had a smaller dispersion force component of the surface free energy than those prepared from the polyacrylatrile homopolymer.